Here goes: (with your answers, please explain why/how you got to that conclusion)

1.) Brigand : Robin Hood::

a. Dwarf : Snow White

b. Outlaw: Lone Ranger

c. Pet: Lassie

d. newspaperman : Superman

2.) Poach : game::

a. pick : berries

b. waste : Time

c. rustle : cattle

d. fry : Omelet

3.) Purloin : thief

a. con : swindler

b. kidnap : baby

c. sirloin : chef

d. serve : hostess

4.) surveillance : Police OFficer

a. walk : park

b. cook : chef

c. cry : woman

d. football : television

e. sad : funeral

Thanks everyone!